Aboveground biomass and carbon stock are related with soil humidity in a mangrove at the Piraquê-Açu River,Southeastern Brazil

In Brazil, few studies have been conducted about the assimilation of carbon and biomass accumulation in mangroves despite its great role as a carbon sink. In this sense, this study aimed to estimate the aboveground biomass (AGB) and carbon stocked by mangrove species in a stretch along the Piraquê-Açu River in southeastern Brazil, and to verify their relation with some soil parameters. For such, the height and diameter of all trees inside six plots of 100 m² were measured and used to quantify AGB through an allometric equation, and soil samples were collected to calculate granulometry, humidity, time of infiltration and permeability. Multiple regressions were used to identify relations between AGB and soil parameters. A total of 296 trees were found in the area and the AGB and carbon assimilated were 2.92 t ha^?1 and 1.46 t ha^?1, respectively. Laguncularia racemosa was the most abundant species and contributed with 61% of these values. Only a positive relation between AGB/carbon of L. racemosa and soil humidity was found, probably due to the substrate characteristics which contain a large concentration of silt/clay, and may store more water and do not yet provide firmness to the roots. By comparison, this mangrove had a low amount of AGB and carbon stocked and has yet to develop structurally. Along with other ecological functions and its associated ecosystem services such as supplying food for the local community, these features highlight the importance to conserve the studied mangrove and the interlinked coastal ecosystems.     

Sand as a relevant fraction in geochemical studies in intertidal environments

Soil and sediment samples from several intertidal environment exposed to different types of contamination were studied to investigate the importance of grain size in relation to the capacity of the substrates to retain trace metals. The unfractionated samples (referred to as bulk samples) were separated into the following grain/size fractions: fine–coarse sand (2?0.100 mm), very fine sand (0.100?0.050 mm), silt (0.050?0.002 mm), and clay (0.002 mm). The sample into its fractions was carried out was in a glove box under high-purity N₂ atmosphere in order to minimize any alterations to the samples. The bulk samples were characterized in terms of physicochemical properties such as pH, redox potential, and grain size. The total organic carbon (TOC), total sulfur (S), iron (Fe) pyrite, Fe, and manganese (Mn), and trace metals lead (Pb), mercury (Hg), chromium (Cr), and nickel (Ni) were analyzed in the bulk samples and in each fraction. The sand fractions were also examined by scanning electron microscopy (SEM). Comparisons of the above parameters were made between fractions and between each fraction and the corresponding bulk sample. The fine–coarse sand fraction contained high levels of the primary elements of the geochemical processes that occur in marine sedimentary environments such as TOC, total Fe, Mn, and S. The net concentrations of these four elements were higher in the fine-coarse sand fraction than in the very fine sand fraction and were similar to the net concentrations in the silt and clay fractions. Detailed SEM analysis of the sand coarse fraction revealed the presence of Fe and aluminum oxyhydroxide coatings in the oxic layers, whereas the framboidal pyrites and coatings observed in the anoxic layers were Fe sulfides. The presence of the various coatings explains why the trace metal concentrations in the sand fine–coarse fraction were similar to those in the clay fraction and higher than those in the very fine sand fraction. The present results highlight the importance of the sand fraction, which is generally disregarded in geochemical and environmental studies of sedimentary layers.     

Leading and lagging: Process safety climate–incident relationships at one year

In order to evaluate the leading and lagging effects of process safety climate on incidents, we correlated safety climate survey data with organizational safety records from before and after the survey time period. We obtained data from a large, multinational organization with manufacturing operations involving a number of complex processes, chemicals, and hazardous substances. A total of 7728 employees from 62 sites responded to a safety climate survey in 2007. Individual responses were aggregated to the site-level and matched to site-level organizational records of process safety incidents 1 year before and 1 year after survey administration. Employees’ perceptions of good routine housekeeping were significantly related to environmental impact incidents as both a leading and a lagging indicator, as well as fires/explosions and property damage outcomes. Employees’ perceptions of systems to prevent backlogs and the extent to which health and safety problems are promptly corrected were also related to environmental releases and fires/explosions. Implications for process safety climate research, organizational survey strategies, and organizational climate change are discussed.     

Finished leather waste chromium acid extraction and anaerobic biodegradation of the products

Due to the amounts of chromium in the leachate resulting from leather leaching tests, chromium sulfate tanned leather wastes are very often considered hazardous wastes. To overcome this problem, one option could be recovering the chromium and, consequently, lowering its content in the leather scrap. With this objective, chromium leather scrap was leached with sulfuric acid solutions at low temperature also aiming at maximizing chromium removal with minimum attack of the leather matrix. The effects of leather scrap dimension, sulfuric acid and sodium sulfate concentration in the solutions, as well as extraction time and temperature on chromium recovery were studied, and, additionally, organic matrix degradation was evaluated. The best conditions found for chromium recovery were leather scrap conditioning using 25 mL of concentrated H₂SO₄/L solution at 293 or 313 K during 3 or 6 days. Under such conditions, 30–60 ± 5% of chromium was recovered and as low as 3–6 ± 1% of the leather total organic carbon (TOC) was dissolved. Using such treatment, the leather scrap area and volume are reduced and the residue is a more brittle material showing enhanced anaerobic biodegradability. Although good recovery results were achieved, due to the fact that the amount of chromium in eluate exceeded the threshold value this waste was still hazardous. Thus, it needs to be methodically washed in order to remove all the chromium de-linked from collagen.     

Can oil prices help estimate commodity futures prices? The cases of copper and silver

There is an extensive literature on modeling the stochastic process of commodity futures. It has been shown that models with several risk factors are able to adequately fit both the level and the volatility structure of observed transactions with reasonable low errors.     

Trace metal concentrations in tissues of two tinamou species in mining areas of Bolivia and their potential as environmental sentinels

Mining has a long history in the Bolivian Andes and has left many tailing piles, from which trace metals may reach surface waters, soils, and biota. The potential of tinamous (Birds: Tinamidae) as sentinels has never been tested before, although their biological and ecological characteristics mean they could well be appropriate bioindicators. We captured 13 and nine individuals of the Ornate Tinamou (Nothoprocta ornata) from two polluted sites (P1 and P2) and 10 and five from control unpolluted sites (NP1 and NP2) and used, for comparative purposes, four specimens bred in captivity. We also captured six specimens of Darwin’s Nothura (Nothura darwinii) from the polluted site, P2. We determined the concentration of As, Cd, Pb, and Sb in feathers, liver, and kidney and conducted histological analyses of liver and kidney. For the Ornate Tinamou, a site effect was found for all trace metals in all tissues, with the highest concentrations at polluted sites. At the P2 site, no differences between the two tinamou species were detected except in some cases where Darwin’s Nothura shows near-double concentrations. In some cases, mean and/or individual values of trace metal concentrations reached toxicity levels at the polluted sites. Thesaurismosis in proximal convoluted renal tubules, probably related to Cd exposure, was observed in 30% of the samples from the P1 site. Significant correlations were observed between all tissues for all trace metals and also for all trace metals in each tissue. Because the species studied are ubiquitous and relatively abundant, we recommend monitoring programs based on feather analysis.     

Isolation and characterization of a Rhodococcus strain with phenol-degrading ability and its potential use for tannery effluent biotreatment

Introduction

Wastewater derived from leather production may contain phenols, which are highly toxic, and their degradation could be possible through bioremediation technologies.

Materials, methods and results

In the present work, microbial degradation of phenol was studied using a tolerant bacterial strain, named CS1, isolated from tannery sediments. This strain was able to survive in the presence of phenol at concentrations of up to 1,000?mg/L. On the basis of morphological and biochemical properties, 16S rRNA gene sequencing, and phylogenetic analysis, the isolated strain was identified as Rhodococcus sp. Phenol removal was evaluated at a lab-scale in Erlenmeyer flasks and at a bioreactor scale in a stirred tank reactor. Rhodococcus sp. CS1 was able to completely remove phenol in a range of 200 to 1,000?mg/L in mineral medium at 30 ± 2?°C and pH 7 as optimal conditions. In the stirred tank bioreactor, we studied the effect of some parameters, such as agitation (200?C600 rpm) and aeration (1?C3?vvm), on growth and phenol removal efficiency. Faster phenol biodegradation was obtained in the bioreactor than in Erlenmeyer flasks, and maximum phenol removal was achieved at 400?rpm and 1 vvm in only 12?h. Furthermore, Rhodococcus sp. CS1 strain was able to grow and completely degrade phenols from tannery effluents after 9?h of incubation.

Conclusion

Based on these results, Rhodococcus sp. CS1 could be an appropriate microorganism for bioremediation of tannery effluents or other phenol-containing wastewaters.     

Injury and loss concentration by sinkings in fishing fleets

Sinkings of fishing vessels, when accompanied by human loss, are accidents which lead to a great social upheaval, especially in the local area where they occur. In order to avoid or reduce these accidents, national governments must include in their legislation for this sector the appropriate safety measures. These resources and their distribution must be assigned in accordance with the needs of the accidentality, this requiring a detailed knowledge of the concentration of accidentality of a country’s fishing sector. In this context, the aim of the present work is twofold: first, to formulate a methodology for the fishing sector of a country, allowing the inequalities in the concentration of sinking accidents to be analysed; and second, to apply this methodology to the Spanish fishing fleet. Thus, two indices are constructed per region and type of fishing, for two variables: fishermen and vessels. Results are obtained both for the concentration of accidents and the associated Lorenz curves. An increase in the inequality in the spatial and functional distribution of these accidents is verified.     

Advances in the recycling of plastic wastes for metallurgical coke production

This paper aims to provide useful knowledge on the use of plastic wastes as additives to coking blends for the production of metallurgical coke. It focuses on the influence that the composition of plastic wastes has upon the development of coal fluidity, the generation of pressure during the coking process and the quality of the cokes produced in a semipilot oven. Several plastic mixtures of two types of thermoplastics, polyolefins (HDPE, LDPE and PP) and aromatic polymers such as PET, were used. The overall addition rate of plastics to a medium-fluid coal blend was 2 wt%. It is shown that polyolefins, weaker modifiers of coal fluidity, may be employed to maintain coke quality but that they have a negative effect on the generation of coking pressure, while plastics of the aromatic type such as PET, a strong modifier of coal fluidity, can be used to counteract the generation of coking pressure. From the results, it is deduced that the protocol developed is useful for determining the optimum amount of each type of polymer (polyolefins and aromatic polymers) that is needed in order to counteract the generation of pressure during the coking process and to maintain the quality of the cokes.     

Effect of water washing on the thermal behavior of rice straw

Rice straw can be used as a renewable fuel for heat and power generation. It is a viable mean of replacing fossil fuels and preventing pollution caused by open burning, especially in the areas where this residual biomass is generated. Nevertheless, the thermal conversion of rice straw can cause some operating problems such as slag formation, which negatively affects thermal conversion systems. So, the main objective of this research is studying the combustion behavior of rice straw samples collected from various regions by applying thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). In addition, the thermal behavior of ashes from rice straw was also analyzed in order to detect their melting points, and ash sintering was detected at different temperatures within the range between 550 and 1000 °C. Since washing rice straw with water could reduce the content of undesirable inorganic compounds related to the ash fusibility, samples of washed rice straw were analyzed under combustion conditions to investigate its differences regarding the thermal behavior of rice straw. The results showed that rice straw washing led to a significant improvement in its thermal behavior, since it reduced the ash contents and sintering formation.